Experiments and Observations on Electricity Made at Philadelphia in America · Benjamin Franklin
_SIR_,
Then if your strips of glass remain whole, you will see that the gold is missing in several places, and instead of it a metallic stain on both the glasses; the stains on the upper and under glass exactly similar in the minutest stroke, as may be seen by holding them to the light; the metal appeared to have been not only melted, but even vitrified, or otherwise so driven into the pores of the glass, as to be protected by it from the action of the strongest _Aqua Fortis_ and _Ag: Regia_. I send you enclosed two little pieces of glass with these metallic stains upon them, which cannot be removed without taking part of the glass with them. Sometimes the stain spreads a little wider than the breadth of the leaf, and looks brighter at the edge, as by inspecting closely you may observe in these. Sometimes the glass breaks to pieces: once the upper glass broke into a thousand pieces, looking like coarse salt. These pieces I send you, were stain'd with _Dutch_ gold. True gold makes a darker stain, somewhat reddish; silver, a greenish stain.
We once took two pieces of thick looking-glass, as broad as a Gunter's scale, and 6 inches long; and placing leaf gold between them, put them betwixt two smoothly plain'd pieces of wood, and fix'd them tight in a book-binder's small press; yet though they were so closely confined, the force of the electrical shock shivered the glass into many pieces. The gold was melted and stain'd into the glass as usual. The circumstances of the breaking of the glass differ much in making the experiment, and sometimes it does not break at all: but this is constant, that the stains in the upper and under pieces are exact counterparts of each other. And though I have taken up the pieces of glass between my fingers immediately after this melting, I never could perceive the least warmth in them. 25. In one of my former papers, I mention'd, that gilding on a book, though at first it communicated the shock perfectly well, yet fail'd after a few experiments, which we could not account for. We have since found, that one strong shock breaks the continuity of the gold in the filleting, and makes it look rather like dust of gold, abundance of its parts being broken and driven off; and it will seldom conduct above one strong shock. Perhaps this may be the reason; when there is not a perfect continuity in the circle, the fire must leap over the vacancies; there is a certain distance which it is able to leap over according to its strength; if a number of small vacancies, though each be very minute, taken together exceed that distance, it cannot leap over them, and so the shock is prevented.
26. From the before mentioned law of electricity, that points, as they are more or less acute, draw on and throw off the electrical fluid with more or less power, and at greater or less distances, and in larger or smaller quantities in the same time, we may see how to account for the situation of the leaf of gold suspended between two plates, the upper one continually electrified, the under one in a person's hand standing on the floor. When the upper plate is electrified, the leaf is attracted and raised towards it, and would fly to that plate were it not for its own points. The corner that happens to be uppermost when the leaf is rising, being a sharp point, from the extream thinness of the gold, draws and receives at a distance a sufficient quantity of the electrical fluid to give itself an electrical atmosphere, by which its progress to the upper plate is stopt, and it begins to be repelled from that plate, and would be driven back to the under plate, but that its lowest corner is likewise a point, and throws off or discharges the overplus of the leaf's atmosphere, as fast as the upper corner draws it on.
Were these two points perfectly equal in acuteness, the leaf would take place exactly in the middle space, for its Weight is a trifle, compared to the power acting on it: But it is generally nearest the unelectrified plate, because, when the leaf is offered to the electrified plate at a distance, the sharpest point is commonly first affected and raised towards it; so that point, from its greater acuteness, receiving the fluid faster than its opposite can discharge it at equal distances, it retires from the electrified plate, and draws nearer to the unelectrified plate, till it comes to a distance where the discharge can be exactly equal to the receipt, the latter being lessened, and the former encreased; and there it remains as long as the globe continues to supply fresh electrical matter. This will appear plain, when the difference of acuteness in the corners is made very great.
Cut a piece of _Dutch_ gold (which is fittest for these experiments on account of its greater strength) into the form of FIG. 10 the upper corner a right angle, the two next obtuse angles, and the lowest a very acute one; and bring this on your plate under the electrified plate, in such a manner as that the right-angled part may be first raised (which is done by covering the acute part with the hollow of your hand) and you will see this leaf take place much nearer to the upper than to the under plate; because, without being nearer, it cannot receive so fast at its right-angled point, as it can discharge at its acute one. Turn this leaf with the acute part uppermost, and then it takes place nearest the unelectrified plate, because otherwise it receives faster at its acute point than it can discharge at its right-angled one. Thus the difference of distance is always proportioned to the difference of acuteness. Take care in cutting your leaf to leave no little ragged particles on the edges, which sometimes form points where you would not have them. You may make this figure so acute below and blunt above, as to need no under plate, it discharging fast enough into the air.
When it is made narrower, as the figure between the pricked lines, we call it the _Golden Fish_, from its manner of acting. For if you take it by the tail, and hold it at a foot or greater horizontal distance from the prime conductor, it will, when let go, fly to it with a brisk but wavering motion, like that of an eel through the water; it will then take place under the prime conductor, at perhaps a quarter or half an inch distance, and keep a continual shaking of its tail like a fish, so that it seems animated. Turn its tail towards the prime conductor, and then it flies to your finger, and seems to nibble it. And if you hold a plate under it at six or eight inches distance, and cease turning the Globe, when the electrical atmosphere of the conductor grows small, it will descend to the plate and swim back again several times with the same fish-like motion, greatly to the entertainment of spectators. By a little practice in blunting or sharpening the heads or tails of these figures, you may make them take place as desired, nearer, or farther from the electrified plate. 27. It is said in section 8, of this paper, that all kinds of common matter are supposed not to attract the electrical fluid with equal strength; and that those called electrics _per se_, as glass, &c. attract and retain it strongest, and contain the greatest quantity. This latter position may seem a paradox to some, being contrary to the hitherto received opinion; and therefore I shall now endeavour to explain it.
28. In order to this, let it first be considered, _that we cannot, by any means we are yet acquainted with, force the electrical fluid thro' glass_. I know it is commonly thought that it easily pervades glass, and the experiment of a feather suspended by a thread in a bottle hermetically sealed, yet moved by bringing a nibbed tube near the outside of the bottle, is alledged to prove it. But, if the electrical fluid so easily pervades glass, how does the vial become _charged_ (as we term it) when we hold it in our hands? Would not the fire thrown in by the wire pass through to our hands, and so escape into the floor? Would not the bottle in that case be left just as we found it, uncharged, as we know a metal bottle so attempted to be charged would be? Indeed, if there be the least crack, the minutest solution of continuity in the glass, though it remains so tight that nothing else we know of will pass, yet the extremely subtile electrical fluid flies through such a crack with the greatest freedom, and such a bottle we know can never be charged: What then makes the difference between such a bottle and one that is sound, but this, that the fluid can pass through the one, and not through the other?[8]
29. It is true there is an experiment that at first sight would be apt to satisfy a slight observer, that the fire thrown into the bottle by the wire, does really pass thro' the glass. It is this: place the bottle on a glass stand, under the prime conductor; suspend a bullet by a chain from the prime conductor, till it comes within a quarter of an inch right over the wire of the bottle; place your knuckle on the glass stand, at just the same distance from the coating of the bottle, as the bullet is from its wire. Now let the globe be turned, and you see a spark strike from the bullet to the wire of the bottle, and the same instant you see and feel an exactly equal spark striking from the coating on your knuckle, and so on spark for spark. This looks as if the whole received by the bottle was again discharged from it. And yet the bottle by this means is charged![9] And therefore the fire that thus leaves the bottle, though the same in quantity, cannot be the very same fire that entered at the wire; for if it were, the bottle would remain uncharged. 30. If the fire that so leaves the bottle be not the same that is thrown in through the wire, it must be fire that subsisted in the bottle, (that is, in the glass of the bottle) before the operation began.
31. If so, there must be a great quantity in glass, because a great quantity is thus discharged even from very thin glass. 32. That this electrical fluid or fire is strongly attracted by glass, we know from the quickness and violence with which it is resumed by the part that had been deprived of it, when there is an opportunity. And by this, that we cannot from a mass of glass draw a quantity of electrical fire, or electrify the whole mass _minus_, as we can a mass of metal. We cannot lessen or increase its whole quantity, for the quantity it has it holds; and it has as much as it can hold. Its pores are filled with it as full as the mutual repellency of the particles will admit; and what is already in, refuses, or strongly repels, any additional quantity. Nor have we any way of moving the electrical fluid in glass, but one; that is, by covering part of the two surfaces of thin glass with non-electrics, and then throwing an additional quantity of this fluid on one surface, which spreading in the non-electric, and being bound by it to that surface, acts by its repelling force on the particles of the electrical fluid contained in the other surface, and drives them out of the glass into the non-electric on that side, from whence they are discharged, and then those added on the charged side can enter. But when this is done, there is no more in the glass, nor less than before, just as much having left it on one side as it received on the other.
33. I feel a want of terms here, and doubt much whether I shall be able to make this part intelligible. By the word _surface_, in this case, I do not mean mere length and breadth without thickness; but when I speak of the upper or under surface of a piece of glass, the outer or inner surface of the vial, I mean length, breadth, and half the thickness, and beg the favour of being so understood. Now, I suppose, that glass in its first principles, and in the Furnace, has no more of this electrical fluid than other common matter: That when it is blown, as it cools, and the particles of common fire leave it, its pores become a vacuum: That the component parts of glass are extremely small and fine, I guess from its never showing a rough face when it breaks, but always a polish; and from the smallness of its particles I suppose the pores between them must be exceeding small, which is the reason that Aqua-fortis, nor any other menstruum we have, can enter to separate them and dissolve the substance; nor is any fluid we know of, fine enough to enter, except common fire, and the electrical fluid.
Now the departing fire leaving a vacuum, as aforesaid, between these pores, which air nor water are fine enough to enter and fill, the electrical fluid (which is every where ready in what we call the non-electrics, and in the non-electric Mixtures that are in the air,) is attracted in: yet does not become fixed with the substance of the glass, but subsists there as water in a porous stone, retained only by the attraction of the fixed parts, itself still loose and a fluid. But I suppose farther, that in the cooling of the glass, its texture becomes closest in the middle, and forms a kind of partition, in which the pores are so narrow, that the particles of the electrical fluid, which enter both surfaces at the same time, cannot go through, or pass and repass from one surface to the other, and so mix together; yet, though the particles of electrical fluid, imbibed by each surface, cannot themselves pass through to those of the other, their repellency can, and by this means they act on one another. The particles of the electrical fluid have a mutual repellency, but by the power of attraction in the glass they are condensed or forced nearer to each other.
When the glass has received and, by its attraction, forced closer together so much of this electrified fluid, as that the power of attracting and condensing in the one, is equal to the power of expansion in the other, it can imbibe no more, and that remains its constant whole quantity; but each surface would receive more, if the repellency of what is in the opposite surface did not resist its entrance. The quantities of this fluid in each surface being equal, their repelling action on each other is equal; and therefore those of one surface cannot drive out those of the other: but, if a greater quantity is forced into one surface than the glass would naturally draw in; this increases the repelling power on that side, and overpowering the attraction on the other, drives out part of the fluid that had been imbibed by that surface, if there be any non-electric ready to receive it: such there is in all cases where glass is electrified to give a shock. The surface that has been thus emptied by having its electrical fluid driven out, resumes again an equal quantity with violence, as soon as the glass has an opportunity to discharge that over-quantity more than it could retain by attraction in its other surface, by the additional repellency of which the vacuum had been occasioned. For experiments favouring (if I may not say confirming) this hypothesis, I must, to avoid repetition, beg leave to refer you back to what is said of the electrical phial in my former papers.
34. Let us now see how it will account for several other appearances.--Glass, a body extremely elastic (and perhaps its elasticity may be owing in some degree to the subsisting of so great a quantity of this repelling fluid in its pores) must, when rubbed, have its rubbed surface somewhat stretched, or its solid parts drawn a little farther asunder, so that the vacancies in which the electrical fluid resides, become larger, affording room for more of that fluid, which is immediately attracted into it from the cushion or hand rubbing, they being supply'd from the common stock. But the instant the parts of the glass so open'd and fill'd have pass'd the friction, they close again, and force the additional quantity out upon the surface, where it must rest till that part comes round to the cushion again, unless some non electric (as the prime conductor) first presents to receive it.[10] But if the inside of the globe be lined with a non-electric, the additional repellency of the electrical fluid, thus collected by friction on the rubb'd part of the globe's outer surface, drives an equal quantity out of the inner surface into that non-electric lining, which receiving it, and carrying it away from the rubb'd part into the common mass, through the axis of the globe and frame of the machine, the new collected electrical fluid can enter and remain in the outer surface, and none of it (or a very little) will be received by the prime conductor. As this charg'd part of the globe comes round to the cushion again, the outer surface delivers its overplus fire into the cushion, the opposite inner surface receiving at the same time an equal quantity from the floor. Every electrician knows that a globe wet within will afford little or no fire, but the reason has not before been attempted to be given, that I know of.
34. So if a tube lined with a [11]non-electric, be rubb'd, little or no fire is obtained from it. What is collected from the hand in the downward rubbing stroke, entering the pores of the glass, and driving an equal quantity out of the inner surface into the non-electric lining: and the hand in passing up to take a second stroke, takes out again what had been thrown into the outer surface, and then the inner surface receives back again what it had given to the non-electric lining. Thus the particles of electrical fluid belonging to the inside surface go in and out of their pores every stroke given to the tube. Put a wire into the tube, the inward end in contact with the non-electric lining, so it will represent the _Leyden_ bottle. Let a second person touch the wire while you rub, and the fire driven out of the inward surface when you give the stroke, will pass through him into the common mass, and return through him when the inner surface resumes its quantity, and therefore this new kind of _Leyden_ bottle cannot so be charged.
But thus it may: after every stroke, before you pass your hand up to make another, let the second person apply his finger to the wire, take the spark, and then withdraw his finger; and so on till he has drawn a number of sparks; thus will the inner surface be exhausted, and the outer surface charged; then wrap a sheet of gilt paper close round the outer surface, and grasping it in your hand you may receive a shock by applying the finger of the other hand to the wire: for now the vacant pores in the inner surface resume their quantity, and the overcharg'd pores in the outer surface discharge that overplus; the equilibrium being restored through your body, which could not be restored through the glass.[12] If the tube be exhausted of air, a non electric lining in contact with the wire is not necessary; for _in vacuo_, the electrical fire will fly freely from the inner surface, without a non-electric conductor: but air resists its motion; for being itself an electric _per se_, it does not attract it, having already its quantity.
So the air never draws off an electric atmosphere from any body, but in proportion to the non-electrics mix'd with it: it rather keeps such an atmosphere confin'd, which from the mutual repulsion of its particles, tends to dissipation, and would immediately dissipate _in vacuo_.--And thus the experiment of the feather inclosed in a glass vessel hermetically sealed, but moving on the approach of the rubbed tube, is explained: When an additional quantity of the electrical fluid is applied to the side of the vessel by the atmosphere of the tube, a quantity is repelled and driven out of the inner surface of that side into the vessel, and there affects the feather, returning again into its pores, when the tube with its atmosphere is withdrawn; not that the particles of that atmosphere did themselves pass through the glass to the feather.----And every other appearance I have yet seen, in which glass and electricity are concern'd, are, I think, explain'd with equal ease by the same hypothesis. Yet, perhaps, it may not be a true one, and I shall be obliged to him that affords me a better.
35. Thus I take the difference between non electrics and glass, an electric _per se_, to consist in these two particulars. 1st, That a non-electric easily suffers a change in the quantity of the electrical fluid it contains. You may lessen its whole quantity by drawing out a part, which the whole body will again resume; but of glass you can only lessen the quantity contain'd in one of its surfaces; and not that, but by supplying an equal quantity at the same time to the other surface; so that the whole glass may always have the same quantity in the two surfaces, their two different quantities being added together. And this can only be done in glass that is thin; beyond a certain thickness we have yet no power that can make this change. And, 2dly, that the electrical fire freely removes from place to place, in and through the substance of a non-electric, but not so through the substance of glass. If you offer a quantity to one end of a long rod of metal, it receives it, and when it enters, every particle that was before in the rod, pushes its neighbour quite to the further end, where the overplus is discharg'd; and this instantaneously where the rod is part of the circle in the experiment of the shock. But glass, from the smallness of its pores, or stronger attraction of what it contains, refuses to admit so free a motion; a glass rod will not conduct a shock, nor will the thinnest glass suffer any particle entring one of its surfaces to pass thro' to the other.
36. Hence we see the impossibility of success, in the experiments propos'd, to draw out the effluvial virtues of a non-electric, as cinnamon for instance, and mixing them with the electrical fluid, to convey them with that into the body, by including it in the globe, and then applying friction, etc. For though the effluvia of cinnamon, and the electrical fluid should mix within the globe, they would never come out together through the pores of the glass, and so go to the prime conductor; for the electrical fluid itself cannot come through; and the prime conductor is always supply'd from the cushion, and that from the floor. And besides, when the globe is filled with cinnamon, or other non-electric, no electrical fluid can be obtain'd from its outer surface, for the reason before-mentioned. I have try'd another way, which I thought more likely to obtain a mixture of the electrical and other effluvia together, if such a mixture had been possible. I placed a glass plate under my cushion, to cut off the communication between the cushion and floor; then brought a small chain from the cushion into a glass of oil of turpentine, and carried another chain from the oil of turpentine to the floor, taking care that the chain from the cushion to the glass touch'd no part of the frame of the machine. Another chain was fix'd to the prime conductor, and held in the hand of a person to be electrised. The ends of the two chains in the glass were near an inch distant from each other, the oil of turpentine between. Now the globe being turn'd, could draw no fire from the floor through the machine, the communication that way being cut off by the thick glass plate under the cushion: it must then draw it through the chains whose ends were dipt in the oil of turpentine.
Text from Project Gutenberg, public domain in the United States.