Chance, Love, and Logic · Charles S. Peirce
IV
When a formula of this kind is discovered, it is no longer called an empirical formula, but a law of Nature; and is sooner or later made the basis of an hypothesis which is to explain it. These simple formulæ are not usually, if ever, exactly true, but they are none the less important for that; and the great triumph of the hypothesis comes when it explains not only the formula, but also the deviations from the formula. In the current language of the physicists, an hypothesis of this importance is called a theory, while the term hypothesis is restricted to suggestions which have little evidence in their favor. There is some justice in the contempt which clings to the word hypothesis. To think that we can strike out of our own minds a true preconception of how Nature acts, in a vain fancy. As Lord Bacon well says: “The subtlety of Nature far exceeds the subtlety of sense and intellect: so that these fine meditations, and speculations, and reasonings of men are a sort of insanity, only there is no one at hand to remark it.” The successful theories are not pure guesses, but are guided by reasons.
The kinetical theory of gases is a good example of this. This theory is intended to explain certain simple formulæ, the chief of which is called the law of Boyle. It is, that if air or any other gas be placed in a cylinder with a piston, and if its volume be measured under the pressure of the atmosphere, say fifteen pounds on the square inch, and if then another fifteen pounds per square inch be placed on the piston, the gas will be compressed to one-half its bulk, and in similar inverse ratio for other pressures. The hypothesis which has been adopted to account for this law is that the molecules of a gas are small, solid particles at great distances from each other (relatively to their dimensions), and moving with great velocity, without sensible attractions or repulsions, until they happen to approach one another very closely. Admit this, and it follows that when a gas is under pressure what prevents it from collapsing is not the incompressibility of the separate molecules, which are under no pressure at all, since they do not touch, but the pounding of the molecules against the piston.
The more the piston falls, and the more the gas is compressed, the nearer together the molecules will be; the greater number there will be at any moment within a given distance of the piston, the shorter the distance which any one will go before its course is changed by the influence of another, the greater number of new courses of each in a given time, and the oftener each, within a given distance of the piston, will strike it. This explains Boyle’s law. The law is not exact; but the hypothesis does not lead us to it exactly. For, in the first place, if the molecules are large, they will strike each other oftener when their mean distances are diminished, and will consequently strike the piston oftener, and will produce more pressure upon it. On the other hand, if the molecules have an attraction for one another, they will remain for a sensible time within one another’s influence, and consequently they will not strike the wall so often as they otherwise would, and the pressure will be less increased by compression.
When the kinetical theory of gases was first proposed by Daniel Bernoulli, in 1738, it rested only on the law of Boyle, and was therefore pure hypothesis. It was accordingly quite naturally and deservedly neglected. But, at present, the theory presents quite another aspect; for, not to speak of the considerable number of observed facts of different kinds with which it has been brought into relation, it is supported by the mechanical theory of heat. That bringing together bodies which attract one another, or separating bodies which repel one another, when sensible motion is not produced nor destroyed, is always accompanied by the evolution of heat, is little more than an induction. Now, it has been shown by experiment that, when a gas is allowed to expand without doing work, a very small amount of heat disappears. This proves that the particles of the gas attract one another slightly, and but very slightly. It follows that, when a gas is under pressure, what prevents it from collapsing is not any repulsion between the particles, since there is none. Now, there are only two modes of force known to us, force of position or attractions and repulsions, and force of motion. Since, therefore, it is not the force of position which gives a gas its expansive force, it must be the force of motion. In this point of view, the kinetical theory of gases appears as a deduction from the mechanical theory of heat. It is to be observed, however, that it supposes the same law of mechanics (that there are only those two modes of force) which holds in regard to bodies such as we can see and examine, to hold also for what are very different, the molecules of bodies. Such a supposition has but a slender support from induction. Our belief in it is greatly strengthened by its connection with the law of Boyle, and it is, therefore, to be considered as an hypothetical inference. Yet it must be admitted that the kinetical theory of gases would deserve little credence if it had not been connected with the principles of mechanics.
The great difference between induction and hypothesis is, that the former infers the existence of phenomena such as we have observed in cases which are similar, while hypothesis supposes something of a different kind from what we have directly observed, and frequently something which it would be impossible for us to observe directly. Accordingly, when we stretch an induction quite beyond the limits of our observation, the inference partakes of the nature of hypothesis. It would be absurd to say that we have no inductive warrant for a generalization extending a little beyond the limits of experience, and there is no line to be drawn beyond which we cannot push our inference; only it becomes weaker the further it is pushed. Yet, if an induction be pushed very far, we cannot give it much credence unless we find that such an extension explains some fact which we can and do observe. Here, then, we have a kind of mixture of induction and hypothesis supporting one another; and of this kind are most of the theories of physics.
Ideas discussed in this chapter
Text from Project Gutenberg, public domain in the United States.