Concept
Isomer
Overview
In chemistry, isomers are molecules or polyatomic ions with an identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism refers to the existence or possibility of isomers.
Isomers do not necessarily share similar chemical or physical properties. Two main forms of isomerism are structural (or constitutional) isomerism, in which bonds between the atoms differ; and stereoisomerism (or spatial isomerism), in which the bonds are the same but the relative positions of the atoms differ.
Isomeric relationships form a hierarchy. Two chemicals might be the same constitutional isomer, but upon deeper analysis be stereoisomers of each other. Two molecules that are the same stereoisomer as each other might be in different conformational forms or be different isotopologues. The depth of analysis depends on the field of study or the chemical and physical properties of interest.
The English word "isomer" () is a back-formation from "isomeric", which was borrowed through German isomerisch from Swedish isomerisk; which in turn was coined from Greek ἰσόμερoς isómeros, with roots isos = "equal", méros = "part".
Overview adapted from Wikipedia (CC BY-SA 4.0; see the article history for authors).
Possible passages
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Still more strongly will a similar presumption exist, when the object itself, as in the case of organized beings, is no primeval agent, but an effect, which depends on a cause or causes for its very existence. The Kinds, therefore, which are called in chemistry simple substances, or elementary natural agents, are the only ones, any of whose properties can with certainty be considered ultimate; and of these the…
John Stuart Mill, A System of Logic, Ratiocinative and Inductive
States what Isomer is.
Two sets of four points each are defined as having the same anharmonic ratio, when (1) each set of four lies in one straight line, and (2) corresponding points of different sets lie two by two on four straight lines through a single point, or when both sets have this relation to any third set[123]. And reciprocally: Two sets of four straight lines are defined as having the same anharmonic ratio when (1) each set of…
Bertrand Russell, An essay on the foundations of geometry
States what Isomer is.
The theory that matter consists of “atoms”, _i.e._ of little bits that cannot be divided, is due to the Greeks, but with them it was only a speculation. The evidence for what is called the atomic theory was derived from chemistry, and the theory itself, in its nineteenth-century form, was mainly due to Dalton. It was found that there were a number of “elements”, and that other substances were compounds of these…
Bertrand Russell, Philosophy
States what Isomer is.
Related ideas
- German language
- Greek language
- Hierarchy
- Physical property
- Molecule
- Oxygen
- Swedish language
- Topology
- Chemistry
- Chemical bond
- DNA
- Atom
- Enantiomer
- Coordination complex
Place in the tradition
Part of Greek language.