Concept
Wave function
Overview
In quantum mechanics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters ψ and Ψ (lower-case and capital psi, respectively).
According to the superposition principle of quantum mechanics, wave functions can be added together and multiplied by complex numbers to form new wave functions and form a Hilbert space. The inner product of two wave functions is a measure of the overlap between the corresponding physical states and is used in the foundational probabilistic interpretation of quantum mechanics, the Born rule, relating transition probabilities to inner products. The Schrödinger equation determines how wave functions evolve over time, and a wave function behaves qualitatively like other waves, such as water waves or waves on a string, because the Schrödinger equation is mathematically a type of wave equation. This explains the name "wave function", and gives rise to wave–particle duality. However, whether the wave function in quantum mechanics describes a kind of physical phenomenon is still open to different interpretations, fundamentally differentiating it from classic mechanical waves.
Wave functions are complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density of measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called normalization. Since the wave function is complex-valued, only its relative phase and relative magnitude can be measured; its value does not, in isolation, tell anything about the magnitudes or directions of measurable observables. One has to apply quantum operators, whose eigenvalues correspond to sets of possible results of measurements, to the wave function ψ and calculate the statistical distributions for measurable quantities.
Wave functions can be functions of variables other than position, such as momentum. The information represented by a wave function that is dependent upon position can be converted into a wave function dependent upon momentum and vice versa, by means of a Fourier transform. Some particles, like electrons and photons, have nonzero spin, and the wave function for such particles includes spin as an intrinsic, discrete degree of freedom; other discrete variables can also be included, such as isospin. When a system has internal degrees of freedom, the wave function at each point in the continuous degrees of freedom (e.g., a point in space) assigns a complex number for each possible value of the discrete degrees of freedom (e.g., z-component of spin). These values are often displayed in a column matrix (e.g., a 2 × 1 column vector for a non-relativistic electron with spin 1⁄2).
Overview adapted from Wikipedia (CC BY-SA 4.0; see the article history for authors).
Possible passages
Found by search and not yet checked by a person; they may only mention the idea in passing.
The axiom can be explained as follows: Let {alpha} and {beta} be the names of two time-systems. The directions of motion in the space of {alpha} due to rest in a point of {beta} is called the '{beta}-direction in {alpha}' and the direction of motion in the space of {beta} due to rest in a point of {alpha} is called the '{alpha}-direction in {beta}.' Consider a motion in the space of {alpha} consisting of a certain…
Alfred North Whitehead, The Concept of Nature The Tarner Lectures Delivered in Trinity College, November 1919
States what Wave function is.
Number, in general, is the quantum in its complete specialisation. Hence we may employ it not only to determine what we call discrete, but what are called continuous magnitudes as well. For that reason even geometry must call in the aid of number, when it is required to specify definite figurations of space and their ratios. (c) _Degree._ 103.] The limit (in a quantum) is identical with the whole of the quantum…
Georg Wilhelm Friedrich Hegel, The Logic of Hegel
States what Wave function is.
The knowledge of the elementary fact enables us to put the problem in an equation. Nothing remains but to deduce from this by combination the complex fact that can be observed and verified. This is what is called _integration_, and is the business of the mathematician. It may be asked why, in physical sciences, generalization so readily takes the mathematical form. The reason is now easy to see.
Henri Poincaré, The Foundations of Science
States what Wave function is.
Related ideas
- Eugene Wigner
- John von Neumann
- Function (mathematics)
- David Bohm
- Momentum
- Real number
- Niels Bohr
- Probability
- Photon
- Quantum mechanics
- Quantum field theory
- Quantum entanglement
- Set (mathematics)
- Special relativity
- Subset
- String theory
- Theory of relativity
- Uncertainty principle
- University of California, Berkeley
- Werner Heisenberg
- Wave–particle duality
- Wave
- Causality
- Born rule
Place in the tradition
Part of Deductive-nomological model.